Hafting of a Neolithic leister: Identification of adhesives from Lolland (Denmark)

Authors

DOI:

https://doi.org/10.7146/dja.v13i1.141566

Keywords:

Birch tar, Hafting technology, Pitch, Fishing equipment, Femern project

Abstract

Birch tar has been identified as the predominant adhesive used for hafting purposes in the European Mesolithic and Neolithic. Its role in the manufacture of composite tools and weapons comprising wooden, bone and flint components attests its importance during these periods. The discovery of birch tar lumps, some bearing tooth imprints, suggests a broader range of functions beyond its adhesive properties. In this study, we present an analysis of five residues from two sites (Syltholm II and Strandholm I) that have been excavated through the Femern project, with the aim to shed light on the adhesives used in relation to their functions. Through chemical analyses, we show that birch tar constitutes the main component of two lumps and one chewed piece. We also found that birch tar served to haft a bone point within leister prongs, providing new information on its previously unknown role in composite fishing tool technology. These findings have significant implications for our understanding of the functional role and performance of birch tar in aquatic environments.

References

Aveling, E. and Heron, C., 1998. Identification of Birch Bark Tar at the Mesolithic Site of Star Carr. Ancient Biomolecules 2, 69-80.

Aveling, E. and Heron, C.P., 1999. Chewing tar in the early Holocene: an archaeological and ethnographic evaluation. Antiquity 73, 579-584. https://doi.org/10.1017/S0003598X00065133

Binder, D., Benoist, F., Bourgeois, G. and Vitry, C., 1990. Identification de brai de bouleau (Betula) dans le Néolithique de Giribaldi (Nice, France) par la spectrométrie de masse. ArchéoSciences, revue d’Archéométrie, 37-42. https://doi.org/10.3406/arsci.1990.881

Bjørnevad, M., Jonuks, T., Bye-Jensen, P., Manninen, M.A., Oras, E., Vahur, S. and Riede, F., 2019. The Life and Times of an Estonian Mesolithic Slotted Bone “Dagger”. Extended Object Biographies for Legacy Objects. Estonian Journal of Archaeology 2, 103-125. https://doi.org/10.3176/arch.2019.2.02

Chaudesaigues-Clausen, S., 2023. Mesolithic persistence and Neolithic emergence at Syltholm II (MLF00906-III). Osseous artefacts before and after 4000 BCE on the coast of Lolland, DenmarkStone Age Fishing in the prehistoric Syltholm Fjord. In: D. Groß and M. Rothstein, eds. Changing Identity in a Changing World. Current Studies on the Stone Age in Northern Europe around 4000 Cal BC. Leiden: Sidestone, 149-164.

Fuchs, C. and Wahl, J., 2013. Kaugummi oder Werkstoff? Birkenpechstücke aus der Pfahlbausiedlung Hornstaad-Hörnle am Bodensee. Denkmalpflege in Baden-Württemberg 42, 240-245. https://doi.org/10.11588/nbdpfbw.2013.4.12747

Grünberg, J.M., Graetsch, H., Baumer, U. and Koller, J., 1999. Untersuchung der mittelpaläolithischen “Harzreste” von Königsaue, Ldkr. Aschersleben-Staßfurt. Jahresschrift für mitteldeutsche Vorgeschichte 81, 7-38. https://doi.org/10.11588/jsmv.1999.1.84040

Hayek, E.W.H., Jordis, U., Moche, W. and Sauter, F., 1989. A bicentennial of betulin. Phytochemistry 28, 2229-2242. https://doi.org/10.1016/S0031-9422(00)97961-5

Hayek, E.W.H., Krenmayr, P. and Lohninger, H., 1990. Identification of Archaeological and Recent Wood Tar Pitches Using Gas Chromatography/Mass Spectrometry and Pattern Recognition. Analytical Chemistry 62, 2038-2043. https://doi.org/10.1021/ac00217a026

Jensen, T.Z.T., Niemann, J., Iversen, K.H., Fotakis, A.K., Gopalakrishnan, S., Vågene, Å.J., Pedersen, M.W., Sinding, M.-H.S., Ellegaard, M.R., Allentoft, M.E., Lanigan, L.T., Taurozzi, A.J., Nielsen, S.H., Dee, M.W., Mortensen, M.N., Christensen, M.C., Sørensen, S.A., Collins, M.J., Gilbert, M.T.P., Sikora, M., Rasmussen, S. and Schroeder, H., 2019. A 5700 year-old human genome and oral microbiome from chewed birch pitch. Nature Communications 10,1-10. https://doi.org/10.1038/s41467-019-13549-9

Kabaciński, J., Henry, A., David, É., Rageot, M., Cheval, C., Winiarska-Kabacińska, M., Regert, M., Mazuy, A. and Orange, F., 2023. Expedient and efficient: an Early Mesolithic composite implement from Krzyż Wielkopolski. Antiquity 97, 295-313. https://doi.org/10.15184/aqy.2023.3

Kashuba, N., Kırdök, E., Damlien, H., Manninen, M.A., Nordqvist, B., Persson, P. and Götherström, A., 2019. Ancient DNA from mastics solidifies connection between material culture and genetics of mesolithic hunter–gatherers in Scandinavia. Communications Biology 2, 1-10. https://doi.org/10.1038/s42003-019-0399-1

Koch, T.J. and Schmidt, P., 2023. Adhesive Strength and Rupture Behaviour of Birch Tars Made with

Different Stone Age Methods. Journal of Paleolithic Archaeology 6 (8), 1-15. https://doi.org/10.1007/s41982-023-00135-1

Kozowyk, P., Poulis, J.A. and Langejans, G.H.J., 2017. Laboratory strength testing of pine wood and birch bark adhesives: A first study of the material properties of pitch. Journal of Archaeological Science: Reports 13, 49-59. https://doi.org/10.1016/j.jasrep.2017.03.006

Larsson, L., Sjöström, A. and Heron, C., 2016. The Rönneholm Arrow : A Find of a Wooden Arrow-tip with Microliths in the Bog Rönneholms Mosse, Central Scania, Southern Sweden. Lund Archaeological Review 22, 7-20.

Little, A., Needham, A., Langley, A. and Elliott, B., 2022. Material and Sensory Experiences of Mesolithic Resinous Substances. Cambridge Archaeological Journal, 1-30. https://doi.org/10.1017/S0959774322000300

Manninen, M.A., Asheichyk, V., Jonuks, T., Kriiska, A., Osipowicz, G., Sorokin, A.N., Vashanau, A., Riede, F. and Persson, P., 2021. Using Radiocarbon Dates and Tool Design Principles to Assess the Role of Composite Slotted Bone Tool Technology at the Intersection of Adaptation and Culture-History. Journal of Archaeological Method and Theory 28, 845-870. https://doi.org/10.1007/s10816-021-09517-7

Mazza, P., Martini, F., Sala, B., Magi, M., Colombini, M., Giachi, G., Landucci, F., Lemorini, C., Modugno, F. and Ribechini, E., 2006. A new Palaeolithic discovery: tar-hafted stone tools in a European Mid-

Pleistocene bone-bearing bed. Journal of Archaeological Science 33, 1310-1318. https://doi.org/10.1016/j.jas.2006.01.006

Mirabaud, S., Pétrequin, A.-M., Pétrequin, P. and Regert, M., 2015. Système de production des adhésifs exploités à Clairvaux VII et Clairvaux XIV. In: P. Pétrequin and A.-M. Pétrequin, eds. Clairvaux et Le “Néolithique Moyen Bourguignon.” Presses universitaires de Franche-Comté: Centre de Recherche Archéologique de la Vallée de l’Ain, Tome 2, 1001-1012.

Måge, B.T., Groß, D., and Kanstrup, M., 2023. The Femern project: a large-scale excavation of a Stone Age landscape. In: D. Groß and M. Rothstein, eds. Changing Identity in a Changing World. Current Studies on the Stone Age in Northern Europe around 4000 cal BC. Leiden: Sidestone, 21–32.

Nardella, F., Landi, N., Degano, I., Colombo, M., Serradimigni, M., Tozzi, C. and Ribechini, E., 2019. Chemical investigations of bitumen from Neolithic archaeological excavations in Central-Southern Italy by gas chromatography/mass spectrometry combined with principal component analysis. Analytical Methods 11, 1449-1459. https://doi.org/10.1039/C8AY02429D

Niekus, M.J.L.T., Kozowyk, P.R.B., Langejans, G.H.J., Ngan-Tillard, D., van Keulen, H., van der Plicht, J., Cohen, K.M., van Wingerden, W., van Os, B., Smit, B.I., Amkreutz, L.W.S.W., Johansen, L., Verbaas, A. and Dusseldorp, G.L., 2019. Middle Paleolithic complex technology and a Neandertal tar-backed tool from the Dutch North Sea. Proceedings of the National Academy of Sciences 116, 22081-22087. https://doi.org/10.1073/pnas.1907828116

Osipowicz, G., Orłowska, J., Bosiak, M., Manninen, M.A., Targowski, P. and Sobieraj, J., 2020. Slotted bone point from Tłokowo – rewritten story of a unique artefact from Mesolithic Poland. Praehistorische Zeitschrift 95, 334-349. https://doi.org/10.1515/pz-2020-0023

Rageot, M., 2015. Les substances naturelles en Méditerranée nord-occidentale (VIe-Ie Millénaire BCE) : chimie et archéologie des matériaux exploités pour leurs propriétés adhésives et hydrophobes (Doctorat). Université Nice Sophia Antipolis.

Rageot, M., Lepère, C., Henry, A., Binder, D., Davtian, G., Filippi, J.-J., Fernandez, X., Guilaine, J., Jallet, F., Radi, G., Thirault, E., Terradas, X. and Regert, M., 2021. Management systems of adhesive materials throughout the Neolithic in the North-West Mediterranean. Journal of Archaeological Science 126 (105309), 1-19. https://doi.org/10.1016/j.jas.2020.105309

Rageot, M., Théry-Parisot, I., Beyries, S., Lepère, C., Carré, A., Mazuy, A., Filippi, J.-J., Fernandez, X., Binder, D. and Regert, M., 2019. Birch Bark Tar Production: Experimental and Biomolecular Approaches to the Study of a Common and Widely Used Prehistoric Adhesive. Journal of Archaeological Method and Theory 26, 276-312. https://doi.org/10.1007/s10816-018-9372-4

Regert, M., Garnier, N., Binder, D. and Pétrequin, P., 2000. Les adhésifs néolithiques : quels matériaux utilisés, quelles techniques de production dans quel contexte social ? L’exemple des adhésifs des sites de Giribaldi et de Chalain. XXèmes Rencontres Internationales d’Archéologie et d’Histoire d’Antibes, 585-604.

Regert, M., Vacher, S., Moulherat, C. and Decavallas, O., 2003. Adhesive Production and Pottery Function During the Iron Age at the Site of Grand Aunay (Sarthe, France)*. Archaeometry 45, 101-120. https://doi.org/10.1111/1475-4754.00098

Reunanen, M., Holmbom, B. and Edgren, T., 1993. Analysis of Archaeological Birch Bark Pitches. Holzforschung 47, 175-177. https://doi.org/10.1515/hfsg.1993.47.2.175

Schmidt, P., Blessing, M.A., Koch, T.J. and Nickel, K.G., 2021. On the performance of birch tar made with different techniques. Heritage Science 9 (140), 1-9. https://doi.org/10.1186/s40494-021-00621-1

Schmidt, P., Koch, T.J., Berthold, C., Lauxmann, F. and Nickel, K.G., 2022. The evolution of strength, elasticity and rupture behaviour of birch tar made with ‘double-pot’ techniques during tar cooking. Archaeo-

metry, 1-14. https://doi.org/10.1111/arcm.12820

Schmidt, P., Koch, T.J., Blessing, M.A., Karakostis, F.A., Harvati, K., Dresely, V. and Charrié-Duhaut, A., 2023. Production method of the Königsaue birch tar documents cumulative culture in Neanderthals. Archaeological and Anthropological Sciences 15 (84), 1-13. https://doi.org/10.1007/s12520-023-01789-2

Skaarup, J. and Grøn, O., 2004. Møllegabet II. A submerged Mesolithic settlement in southern Denmark. With contributions by Sarah Mason, Lisa Hodgetts, Peter Rowley-Conwy and Annica Cardell. Leiden:

Archaeopress.

Stafseth, T. and Groß, D., 2023. Stone Age Fishing in the prehistoric Syltholm Fjord. In: D. Groß and M. Rothstein, eds. Changing Identity in a Changing World. Current Studies on the Stone Age in Northern Europe around 4000 Cal BC. Leiden: Sidestone, 235-248.

Vahur, S., Kriiska and A., Leito, I., 2011. Investigation of the adhesive residue on the flint insert and the adhesive lump found from the Pulli early Mesolithic settlement site (Estonia) by micro-ATR-FT-IR spectroscopy. Estonian Journal of Archaeology 15, 3-17. https://doi.org/10.3176/arch.2011.1.01

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Published

2024-01-19

How to Cite

Koch, T. J., Groß, D., Måge, B. T., & Little, A. (2024). Hafting of a Neolithic leister: Identification of adhesives from Lolland (Denmark). Danish Journal of Archaeology, 13(1), 1–8. https://doi.org/10.7146/dja.v13i1.141566